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Pre K is typically 3-5 years old so you got a while before you have to figure it out. Depending on your day you can do school before or after your work. Once the get to be able to work independently they can school while you work.
2 is very young just play and if your interested montessori method is a nice start
Research shows that children under 7 learn best through play & that adult-led and structured academics are best held off until then. I'd recommend reading How Children Learn by John Holt and Free to Learn by Peter Gray. PLAY IS LEARNING! And the only curriculum you need is the real world.
Learning to write = play-doh, large body movements, digging in the sand, crafts, drawing in sand/salt, finger painting, coloring. Learning to read = word games, rhyming, talking about letter sounds, large body movements, making up your own language/words, labeling common words around the house. And most importantly read lots of books & have them available for your children to browse. Math = counting, sorting, cooking, baking, blocks, legos, puzzles, putting things together/taking them apart, or exploring motions such as flipping. GAMESCHOOLING is an excellent way to learn while having fun! Candy land = colors Uno = colors and numbers High ho cherry-o = counting and colors Yahtzee = math Bananagrams = letter recognition and spelling
Do it on your days off. And for the days you work maybe add some activity pages and some flash cards. But mainly at this stage play is the best schooling